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The Marlow Advanced Thermoelectric Material Program

By Hylan B. Lyon, Jr., Ph.D.
Materials Research Development
Marlow Industries, Inc.,

Volume 1, Issue 1

Introduction:
A strategic goal of Marlow Industries, Inc. is to maintain and improve our leadership in thermoelectric products and materials performance. This portion of the web site will explore the nature of leadership in materials performance and its footprint in the products and services we offer. Thermoelectric technology has stagnated, in a sense, with very little improvement for nearly 30 years... until recently. One goal of this section therefore will be to provide you, the visitor to Marlow Industries via the web, with some insight into the field of materials science and how it pertains to the development of our products.

Plastic Deformation:
One of the most famous lines in modern movies is from "The Graduate" written by Buck Henry, "Plastics", "There is a great future in plastics". This line conveyed the irony wrapped up in the succeeding generation's advise. The stagnation in thermoelectrics in each of several 30-50 year periods in its nearly 200 year life has been immersed in similar intergenerational irony.

We inherited an approach that taught that the single crystal thermoelectric materials of the Bismuth Telluride alloy family were the most efficient materials. That was true through that era. The reason it was true was because the material we use is highly anisotropic; "different in different directions". The material is almost twice as efficient in one crystallographic direction as it is in the other. You need a single crystal to get the orientation you need. Unfortunately, a single crystal of this material is very fragile, and we were caught with a trade-off between fragility or performance - take your pick.

Marlow Industries and several of its competitors, independently recognized over the past few years, that the constraints drawn from these past words of wisdom were no longer valid.

It is possible to get high degrees of orientation with grains of our material the size of sand or smaller, when they are densified properly. Materials composed of fine grains in this manner are very durable and can exhibit high performance.

Improper densification results in randomness in orientation and impurities on the surfaces. The combination of these two phenomena was catastrophic on performance. The success in avoiding these results took the dedication of several generations of researchers, but it happened.

As a result many of us learned, slowly and surely, that orientation could be achieved, and that the debilitating effect of the surface of the grain could be overcome. We are today, bringing those results to market.

MAM: Micro-Alloyed Material:
MAM is the acronym in Marlow Industries for our fine grain, high performance material. We have not measured any material in our laboratory with higher figure of merit than MAM. We have also proven the material's mechanical strength. We have tried to measure all material in production in the world as a basis of comparison for this statement. Our doors are open. We will measure any competitor's material we can properly acquire and report on the results scientifically, as is possible.

Marlow Industries, has thousands of hours of testing on MAM and is providing our customers with the details they need to qualify the devices fabricated from this material. The results when the day is done are gratifying. This is not to say that introducing a new material into a market, which has relied on another format for so long, is trouble free. Believe us it wasn't, but when the activity settled out, meaning when all of the downstream processes were optimized and released to production, we have proven to ourselves that this is the path to the future. We have high expectations for what we can do next.

In addition to increased performance, an additional benefit of MAM is it opens the door for several innovations in downstream processing and assembly. This translates into an exciting opportunity to engage our customers early in the design cycle and explore design formats, and assembly techniques, which result in new, mutually beneficial cost/performance options.

 

 

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